Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and 
related compounds

Fuge, Felix; Lehmann, Christian W.; Rust, Jörg; Mohr, Fabian

doi:10.1016/j.jorganchem.2009.03.026

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Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds

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Lehmann, Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Rust, Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fuge, F., Lehmann, C. W., Rust, J., & Mohr, F. (2009). Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds. Journal of Organometallic Chemistry, 694(15), 2395-2401. doi:10.1016/j.jorganchem.2009.03.026.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8EA3-A

Abstract

The palladacycle [Pd(μ-O₂CMe){κ²C,N-4-MeC₆H₃N(Me)NO}]₂ undergoes bridge cleavage reactions with a variety of compounds containing donor functionalities including thioamides, 8-hydroxyquinoline, thioureas, selenoureas, acetylacetone derivatives, dithiocarbamates, xanthates, as well as bidentate N-donors to afford either monomeric, neutral Pd(II) complexes or monocationic complexes in high yields. A series of 15 different complexes was prepared and fully characterised spectroscopically and, in some cases, by X-ray diffraction. It was also found that in solution the dithiocarbamato complex undergoes a disproportionation reaction to give a bis(cyclometallated) complex.