Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and 
related compounds

Fuge, Felix; Lehmann, Christian W.; Rust, Jörg; Mohr, Fabian

doi:10.1016/j.jorganchem.2009.03.026

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds

MPS-Authors

/persons/resource/persons58744

Lehmann, Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58946

Rust, Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

公開されているフルテキストはありません

付随資料 (公開)

There is no public supplementary material available

引用

Fuge, F., Lehmann, C. W., Rust, J., & Mohr, F. (2009). Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds. Journal of Organometallic Chemistry, 694(15), 2395-2401. doi:10.1016/j.jorganchem.2009.03.026.

引用: https://hdl.handle.net/11858/00-001M-0000-000F-8EA3-A

要旨

The palladacycle [Pd(μ-O₂CMe){κ²C,N-4-MeC₆H₃N(Me)NO}]₂ undergoes bridge cleavage reactions with a variety of compounds containing donor functionalities including thioamides, 8-hydroxyquinoline, thioureas, selenoureas, acetylacetone derivatives, dithiocarbamates, xanthates, as well as bidentate N-donors to afford either monomeric, neutral Pd(II) complexes or monocationic complexes in high yields. A series of 15 different complexes was prepared and fully characterised spectroscopically and, in some cases, by X-ray diffraction. It was also found that in solution the dithiocarbamato complex undergoes a disproportionation reaction to give a bis(cyclometallated) complex.