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Peri-Diaurated Naphthalene: Synthesis and Reactions of a New Class of Organogold(I) Complexes Containing Bridging, Dianionic Naphthalenediyl Ligands

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Rust,  Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Meyer, N., Lehmann, C. W., Lee, T.-K.-M., Rust, J., Yam, V.-W.-W., & Mohr, F. (2009). Peri-Diaurated Naphthalene: Synthesis and Reactions of a New Class of Organogold(I) Complexes Containing Bridging, Dianionic Naphthalenediyl Ligands. Organometallics, 28(10), 2931-2934. doi:10.1021/om9002335.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8EB7-D
Abstract
The dinuclear gold(I) compound [Au2(μ-C10H6){μ-Ph2P(CH2)2PPh2}] was prepared in high yield by the reaction of 1,8-bis(trimethylstannyl)naphthalene with [Au2Cl2(μ-Ph2P(CH2)2PPh2)]. Oxidative addition with halogens results in the formation of the dihalodigold(II) complexes [Au2(X)2(μ-C10H6){μ-Ph2P(CH2)2PPh2}] (X = Cl, Br, I) containing a gold−gold bond.