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Characterization of Key Intermediates in a Complex Organocatalytic Cascade Reaction Using Mass Spectrometry

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Schrader,  Wolfgang
Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Handayani,  Peni Purwa
Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Zhou,  Jian
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Schrader, W., Handayani, P. P., Zhou, J., & List, B. (2009). Characterization of Key Intermediates in a Complex Organocatalytic Cascade Reaction Using Mass Spectrometry. Angewandte Chemie International Edition, 48(8), 1463-1466. doi:10.1002/anie.200804353.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8F07-F
Abstract
Chemical scrabble: Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one‐pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates.