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Journal Article

Iron-catalyzed addition of Grignard reagents to activated vinyl cyclopropanes

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Sherry,  Benjamin D.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Sherry, B. D., & Fürstner, A. (2009). Iron-catalyzed addition of Grignard reagents to activated vinyl cyclopropanes. Chemical Communications, (46), 7116-7118. doi:10.1039/B918818E.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-8F2D-C
Abstract
A highly regioselective iron-catalyzed addition of branched primary, secondary or tertiary alkyl Grignard reagents to activated vinyl cyclopropanes is described, which likely proceeds by a direct addition mechanism as opposed to single electron transfer or an iron-allyl based process.