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Journal Article

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

MPS-Authors

Marek,  Ilan
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Masarwa, A., Fürstner, A., & Marek, I. (2009). Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters. Chemical Communications, (38), 5760-5762. doi:10.1039/B910465H.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-8F31-F
Abstract
Pd(II)- and Pt(II)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.