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A versatile protocol for Stille−Migita cross coupling reactions

MPS-Authors
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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Funel,  Jaques-Alexis
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Tremblay,  Martin
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Bouchez,  Laure C.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Nevado,  Cristina
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Waser,  Mario
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Ackerstaff,  Jens
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Stimson,  Christopher C.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., Funel, J.-A., Tremblay, M., Bouchez, L. C., Nevado, C., Waser, M., et al. (2008). A versatile protocol for Stille−Migita cross coupling reactions. Chemical Communications, (25), 2873-2875. doi:10.1039/B805299A.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-9009-6
Abstract
The combination of catalytic amounts of [Pd(PPh3)4], copper thiophene-2-carboxylate (CuTC) and [Ph2PO2][NBu4] allowed a series of exigent Stille–Migita reactions to be performed with high yields; as the protocol is fluoride free, a variety of O-silyl and C-silyl groups remained intact.