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Pseudomorphic Transformation of Highly Ordered Mesoporous Co3O4 to CoO via Reduction with Glycerol

MPS-Authors
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Tüysüz,  Harun
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Liu,  Yong
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Weidenthaler,  Claudia
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schüth,  Ferdi
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Tüysüz, H., Liu, Y., Weidenthaler, C., & Schüth, F. (2008). Pseudomorphic Transformation of Highly Ordered Mesoporous Co3O4 to CoO via Reduction with Glycerol. Journal of the American Chemical Society, 130(43), 14108-14110. doi:10.1021/ja806202v.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-90AF-0
Abstract
In this report, we describe the exploration of possibilities for a pseudomorphic reduction of ordered mesoporous metal oxides by high temperature treatment with glycerol, which was most thoroughly studied as an example of the reaction of Co3O4 to CoO. It was found that the glycerol process is a gentle reduction procedure, which maintains the framework topology on the mesoscale while changing the oxidation state and the structure at the atomic scale.