Highly Enantioselective Transfer Hydrogenation of α,β-Unsaturated Ketones

Martin, Nolwenn J. A.; List, Benjamin

doi:10.1021/ja065708d

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Highly Enantioselective Transfer Hydrogenation of α,β-Unsaturated Ketones

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Martin, Nolwenn J. A.
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Martin, N. J. A., & List, B. (2006). Highly Enantioselective Transfer Hydrogenation of α,β-Unsaturated Ketones. Journal of the American Chemical Society, 128(41), 13368-13369. doi:10.1021/ja065708d.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-9369-0

Abstract

We describe an efficient and highly enantioselective conjugate transfer hydrogenation of α,β-unsaturated ketones that is catalyzed by a salt made from tert-butyl valinate and a recently introduced powerful chiral phosphoric acid catalyst (TRIP).