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CatalyticAasymmetric Transfer Hydrogenation of α-Ketoesters with Hantzsch Esters

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Yang,  Jung Woon
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Yang, J. W., & List, B. (2006). CatalyticAasymmetric Transfer Hydrogenation of α-Ketoesters with Hantzsch Esters. Organic Letters, 8(24), 5653-5655. doi:10.1021/ol0624373.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-93D9-5
Abstract
C2-symmetric chiral copper(II)-bisoxazolines function as alcohol dehydrogenase mimics and catalyze highly enantioselective transfer hydrogenations of α-ketoesters with Hantzsch esters as a synthetic NADH analogue to give α-hydroxy esters in excellent enantioselectivities.