English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

(PPh3)3RhCNB(CF3)3 and (PPh3)3RhNCB(CF3)3:  Isocyano- and Cyanoborate Complexes of Tris(triphenylphosphine)rhodium(I)

MPS-Authors
/persons/resource/persons58744

Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Ressource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Finze, M., Bernhardt, E., Willner, H., & Lehmann, C. W. (2006). (PPh3)3RhCNB(CF3)3 and (PPh3)3RhNCB(CF3)3:  Isocyano- and Cyanoborate Complexes of Tris(triphenylphosphine)rhodium(I). Organometallics, 25(12), 3070-3075. doi:10.1021/om060135z.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-944F-4
Abstract
The reactions of K[(CF3)3BNC] and K[(CF3)3BCN] with (PPh3)3RhCl in ethanol resulted in the rhodium(I) complexes (PPh3)3RhNCB(CF3)3 and (PPh3)3RhCNB(CF3)3, respectively. Their 15N-labeled isotopomers were synthesized from the corresponding borate anions. The complexes were characterized by UV, Raman, and multi-NMR spectroscopy, and the crystal structures were obtained. The spectroscopic and structural data are compared to those of the potassium borates and to related rhodium(I) complexes.