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Journal Article

Advances in Iron Catalyzed Cross Coupling Reactions

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Martin,  Rubén
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., & Martin, R. (2005). Advances in Iron Catalyzed Cross Coupling Reactions. Chemistry Letters, 34(5), 624-629. doi:10.1246/cl.2005.624.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-94A1-A
Abstract
This account summarizes recent developments in the use of cheap, benign, and non-toxic iron salts as precatalysts for various cross coupling reactions. Although not yet nearly as mature as their palladium- or nickel-catalyzed counterparts, these transformations provide efficient and scalable solutions for many types of C–C-bond formations. Selected applications to the total synthesis of bioactive natural products illustrate the present state of the art.