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Journal Article

Cross-Coupling of Alkyl Halides with Aryl Grignard Reagents Catalyzed by a Low-Valent Iron Complex

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Martin,  Rubén
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Martin, R., & Fürstner, A. (2004). Cross-Coupling of Alkyl Halides with Aryl Grignard Reagents Catalyzed by a Low-Valent Iron Complex. Angewandte Chemie, International Edition, 43(30), 3955-3957. doi:10.1002/anie.200460504.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-96DF-0
Abstract
A striking reversal of the usual reactivity pattern of aryl Grignard reagents is observed for reactions in the presence of catalytic amounts of the “bare” ferrate complex [Li(tmeda)]2[Fe(C2H4)4] (1). Highly reduced iron–magnesium clusters may play a decisive role in the exceptionally facile and chemoselective cross-coupling reaction with alkyl halides.