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Metallocene‐Catalyzed C7‐Linkage in the Hydrooligomerization of Norbornene by σ‐Bond Metathesis: Insight into the Microstructure of Polynorbornene

MPS-Authors
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Karafilidis,  Christos
Research Department Fink, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Hermann,  Holger
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Rufiñska,  Anna
Service Department Mynott (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Gabor,  Barbara
Service Department Mynott (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Mynott,  Richard J.
Service Department Mynott (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Breitenbruch,  Georg
Service Department Belder (GC, HPLC), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Weidenthaler,  Claudia
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Rust,  Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Joppek,  Werner
Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Thiel,  Walter
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fink,  Gerhard
Research Department Fink, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Karafilidis, C., Hermann, H., Rufiñska, A., Gabor, B., Mynott, R. J., Breitenbruch, G., et al. (2004). Metallocene‐Catalyzed C7‐Linkage in the Hydrooligomerization of Norbornene by σ‐Bond Metathesis: Insight into the Microstructure of Polynorbornene. Angewandte Chemie International Edition, 43(18), 2444-2446. doi:10.1002/anie.200353454.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-9767-5
Abstract
An unusual linkage: The zirconocene‐catalyzed hydrooligomerization of norbornene proceeds by σ‐bond metathesis to form a 2‐exo,7′‐syn linkage (as evident in the pentamer shown). The oligomers were characterized by gas chromatography, NMR spectroscopy , X‐ray crystallography, and DFT calculations.