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Syntheses and structures of [(Me3N)3SiNHLi]4, (C4H8O)Al[NHSi(NMe2)3]3, ((Me2N)3SiNH)3Al and Li(THF)2+[((Me2N)3SiNH)4 Al]-

MPS-Authors
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Rovai,  Riccardo
Research Group Bradley, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Krüger,  Carl
Service Department Krüger (XRAY), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Bradley, J. S., Cheng, F., Archibald, S. J., Supplit, R., Rovai, R., Lehmann, C. W., et al. (2003). Syntheses and structures of [(Me3N)3SiNHLi]4, (C4H8O)Al[NHSi(NMe2)3]3, ((Me2N)3SiNH)3Al and Li(THF)2+[((Me2N)3SiNH)4 Al]-. Dalton Transactions, (9), 1846-1851. doi:10.1039/B209605F.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-9905-2
Abstract
The preparation of lithium tris(dimethylamino)silylamide, [(Me3N)3SiNHLi]4, 2, and its reaction with aluminium trichloride to give tris(dimethylamino)silylamino)(tetrahydrofuran)alane, (C4H8O)Al[NHSi(NMe2)3]3, 3, and bis(tetrahydrofuran)lithium tetrakis(tris(dimethylamino)silylamino)alanate, Li(THF)2+[((Me2N)3SiNH)4Al], 6, is reported, together with the crystal structures of 2, 3 and 6. Tris(dimethylamino)alane, ((Me2N)3SiNH)3Al, was obtained by reaction of tris(dimethylamino)silylamine with aluminium triethyl. The ammonolytic gelation of 3 to an imidoaluminosilicate gel is also described.