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[Co(CO)5][(CF3)3BF]: A Stable Salt of a Homoleptic Trigonal‐Bipyramidal Metal–Carbonyl Cation

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Bernhardt, E., Finze, M., Willner, H., Lehmann, C. W., & Aubke, F. (2003). [Co(CO)5][(CF3)3BF]: A Stable Salt of a Homoleptic Trigonal‐Bipyramidal Metal–Carbonyl Cation. Angewandte Chemie International Edition, 42(18), 2077-2079. doi:10.1002/anie.200250780.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-9911-6
Abstract
Cobalt takes to superacid: By using the superacid system (CF3)3BCO and anhydrous HF the title complex (see structure O blue, C black, Co cyan, F red, B light brown) is formed in a one pot reaction of [Co2(CO)8]. The oxidizing agent is postulated to be H2F+solv. which is generated in situ.