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Oxazolines as chiral building blocks for imidazolium salts and N-heterocyclic carbene ligands

MPS-Authors
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Glorius,  Frank
Research Group Glorius, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Altenhoff,  Gereon
Research Group Glorius, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Glorius, F., Altenhoff, G., Goddard, R., & Lehmann, C. W. (2002). Oxazolines as chiral building blocks for imidazolium salts and N-heterocyclic carbene ligands. Chemical Communications, (22), 2704-2705. doi:10.1039/B208045A.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-996D-7
Abstract
Enantiomerically pure imidazolium triflates can be readily prepared from bioxazolines and oxazolineimines; deprotonation of imidazolium triflate 2 gives a chiral N-heterocyclic carbene that can act as a ligand in a catalytically active palladium complex.