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Enantioselective hydrogenation of enamides catalyzed by chiral rhodium-monodentate phosphite complexes

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Reetz,  M. T.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58814

Mehler,  G.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58816

Meiswinkel,  A.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58993

Sell,  T.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Reetz, M. T., Mehler, G., Meiswinkel, A., & Sell, T. (2002). Enantioselective hydrogenation of enamides catalyzed by chiral rhodium-monodentate phosphite complexes. Tetrahedron Letters, 43(44), 7941-7943. doi:10.1016/S0040-4039(02)01838-5.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-997D-3
Abstract
Chiral monophosphites derived from BINOL are cheap and efficient ligands in the Rh-catalyzed hydrogenation of N-acyl enamides, providing amines with high degrees of enantioselectivity (up to 97.0% ee). (C) 2002 Elsevier Science Ltd. All rights reserved.