Microwave-assisted synthesis of pinacol boronates from aryl chlorides catalyzed 
by a palladium/imidazolium salt system

Fürstner, A.; Seidel, G.

doi:10.1021/ol0171463

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Microwave-assisted synthesis of pinacol boronates from aryl chlorides catalyzed by a palladium/imidazolium salt system

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Fürstner, A.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Seidel, G.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., & Seidel, G. (2002). Microwave-assisted synthesis of pinacol boronates from aryl chlorides catalyzed by a palladium/imidazolium salt system. Organic Letters, 4(4), 541-543. doi:10.1021/ol0171463.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-9A15-3

Abstract

Aryl chlorides bearing electron-withdrawing groups react with bis(pinacol)borane 1 to give aryl boronates in good to excellent yields in the presence of a catalyst formed in situ from Pd(OAc)(2) and the imidazolium chloride 2. The reaction is greatly accelerated when carried out under microwave heating.