A chemo- and stereoselective reduction of cycloalkynes to (E)- cycloalkenes

Fürstner, A.; Radkowski, K.

doi:10.1039/B207169J

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A chemo- and stereoselective reduction of cycloalkynes to (E)- cycloalkenes

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Fürstner, A.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Radkowski, K.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., & Radkowski, K. (2002). A chemo- and stereoselective reduction of cycloalkynes to (E)- cycloalkenes. Chemical Communications, (18), 2182-2183. doi:10.1039/B207169J.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-9A45-8

Abstract

A stereoselective entry into (E)-cycloalkenes is described, comprising the ring closing alkyne metathesis (RCAM) of suitable diynes, a ruthenium-catalyzed trans-selective hydrosilylation of the cycloalkynes thus formed, followed by a desilylation of the resulting vinylsilanes mediated by AgF.