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Labelling of [Leu5]-enkephalin with organometallic Mo complexes by solid-phase synthesis

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van Staveren,  D. R.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

van Staveren, D. R., & Metzler-Nolte, N. (2002). Labelling of [Leu5]-enkephalin with organometallic Mo complexes by solid-phase synthesis. Chemical Communications, (13), 1406-1407. doi:10.1039/b203128k.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-9A53-8
Abstract
The neuropeptide leucine-enkephalin ([Leu(5)]-enkephalin) has been covalently labelled with the two organometallic Mo carbonyl complexes Mo(R-His)(allyl)(CO)(2) (His = N-delta,N,O- L- histidinate) and Mo(R-bpa)(CO)(3) (bpa = bis(2-picolyl) amine) on the resin as the last step of a solid-phase synthesis scheme and in solution.