Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based 
ligand

Khan, S.; Samuel, P. P.; Reent, M.; Dieterich, J. M.; Mata, R. A.; Demers, J. P.; Lange, A.; Roesky, H. W.; Stalke, D.

doi:10.1039/c2cc31214j

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Journal Article

Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand

MPS-Authors

Demers, J. P.
Research Group of Solid-State NMR, MPI for Biophysical Chemistry, Max Planck Society;

Lange, A.
Research Group of Solid-State NMR, MPI for Biophysical Chemistry, Max Planck Society;

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http://pubs.rsc.org/en/content/articlepdf/2012/cc/c2cc31214j?page=search
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1478357_Supplement_2.txt
(Supplementary material), 44KB

Citation

Khan, S., Samuel, P. P., Reent, M., Dieterich, J. M., Mata, R. A., Demers, J. P., et al. (2012). Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand. Chemical communications, 48(40), 4890-4892. doi:10.1039/c2cc31214j.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-9DDA-6

Abstract

Herein we report the syntheses of terminal Sn(II) (3) and Ge(II) (4) hydrides from the corresponding chloride precursors [{2,6-iPr2C6H3NCMe}2C6H3MCl] (M = Sn (1), Ge (2)) using [K{B(sec-Bu)3}H] as a hydrogenating agent. Combination of steric shielding and intramolecular N → M interactions resulted in the protection of M(II)–H bonds.