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Journal Article

Diastereodivergent De-epimerization in Catalytic Asymmetric Allylic Alkylation

MPS-Authors
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Audisio,  Davide
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Luparia,  Marco
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Oliveira,  Teresa
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Klütt,  Dina
Service Department Schulze (GC, HPLC), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Maulide,  Nuno
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Audisio, D., Luparia, M., Oliveira, T., Klütt, D., & Maulide, N. (2012). Diastereodivergent De-epimerization in Catalytic Asymmetric Allylic Alkylation. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(29), 7314-7317. doi:10.1002/anie.201202853.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0010-20E2-9
Abstract
Diastereomers made to order: In an unprecedented ligand-controlled process a racemic mixture of four stereoisomers can be converted with high selectivity into each one of the diastereomers of the product, at will (see scheme). The mechanism of this deracemization of epimers, that is, a de-epimerization, was also studied.