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Facile carbon–sulfur bond cleavage in diarylsulfonium ylides: a catalytic sulfur-to-silicon group transfer

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Huang,  Xueliang
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Maulide,  Nuno
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Huang, X., Goddard, R., & Maulide, N. (2013). Facile carbon–sulfur bond cleavage in diarylsulfonium ylides: a catalytic sulfur-to-silicon group transfer. Chemical Communications, 2-10. doi:10.1039/C2CC35762C.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0010-20F0-9
Abstract
An unusual cleavage of the non-ylidic carbon–sulfur bond of a sulfonium ylide is reported. The reaction can be catalysed by a variety of palladium(II) complexes under mild conditions. Preliminary results show that coordination of the ylide to the metal center results in significant structural changes.