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Journal Article

Modeling Zeolites with Metal-Supported Two-Dimensional Aluminosilicate Films

MPS-Authors
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Boscoboinik,  Anibal
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Yu,  Xin
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Yang,  Bing
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Shaikhutdinov,  Shamil Kamilovich
Chemical Physics, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21524

Freund,  Hans-Joachim
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Citation

Boscoboinik, A., Yu, X., Yang, B., Fischer, F. D., Włodarczyk, R., Sierka, M., et al. (2012). Modeling Zeolites with Metal-Supported Two-Dimensional Aluminosilicate Films. Angewandte Chemie International Edition, 51(24), 6005-6008. doi:10.1002/anie.201201319.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0010-241E-7
Abstract
Flat pore models: Thin, well-defined aluminosilicate films with tetrahedral [SiO4/2] and [AlO4/2⁻] building blocks that are weakly bound to an underlying metal support contain highly acidic bridging OH species, which exhibit H–D exchange (see picture; Si yellow, O red, Al gray, C black, H white). These films are a model system for surface-science studies of the inner walls of zeolite pores.