English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Efficient formation and cleavage of disilanes by potassium-graphite. Silylation with silyl metal reagents

MPS-Authors
There are no MPG-Authors available
External Resource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Fürstner, A., & Weidmann, H. (1988). Efficient formation and cleavage of disilanes by potassium-graphite. Silylation with silyl metal reagents. Journal of Organometallic Chemistry, 354(1), 15-21. doi:10.1016/0022-328X(88)80634-X.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0010-259D-0
Abstract
Potassium-graphite laminate (C8K) very rapidly forms disilanes from chlorosilanes and then rapidly cleaves the disilanes to give silyl potassium reagents which can be converted into potassium silyl cuprates, -manganates, and -vanadates that are useful for nucleophilic substitution and addition reactions.