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Catalytic Asymmetric Epoxidation of 2-Cyclopentenones

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Lee,  Anna
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Reisinger,  Corinna M.
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Lee, A., Reisinger, C. M., & List, B. (2012). Catalytic Asymmetric Epoxidation of 2-Cyclopentenones. Advanced Synthesis & Catalysis, 354(9), 1701-1706. doi:10.1002/adsc.201200072.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0010-3A45-9
Abstract
The first highly efficient asymmetric epoxidation of 2-cyclopentenones has been developed. Using a newly designed and readily available Cinchona amine catalyst, 2-cyclopentenones are reacted with hydrogen peroxide to give the corresponding epoxycyclopentanones in high yields and excellent enantioselectivities.