English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Asymmetric Counteranion-Directed Catalytic Hosomi–Sakurai Reaction

MPS-Authors
/persons/resource/persons58786

Mahlau,  Manuel
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58564

Garcia-Garcia,  Pilar
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58764

List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Locator
There are no locators available
Fulltext (public)
There are no public fulltexts available
Supplementary Material (public)
There is no public supplementary material available
Citation

Mahlau, M., Garcia-Garcia, P., & List, B. (2012). Asymmetric Counteranion-Directed Catalytic Hosomi–Sakurai Reaction. Chemistry-a European Journal, 18(51), 16283-16287. doi:10.1002/chem.201203623.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0010-81E3-5
Abstract
Counteranion control enables the enantioselective, organo Lewis acid catalyzed Hosomi–Sakurai reaction of (hetero)aromatic aldehydes and allylsilanes using an easily handled disulfonimide precatalyst (see scheme). The key to the success of this system is to turn the usually undesired silylium ion catalysis into the desired catalytic regime and pair the cation with an enantiopure disulfonimide anion, thereby applying the concept of asymmetric counteranion-directed catalysis.