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A Functional-Group-Tolerant Catalytic trans Hydrogenation of Alkynes

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Radkowski,  Karin
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Sundararaju,  Basker
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Radkowski, K., Sundararaju, B., & Fürstner, A. (2013). A Functional-Group-Tolerant Catalytic trans Hydrogenation of Alkynes. Angewandte Chemie International Edition, 52(1), 355-360. doi:10.1002/anie.201205946.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000E-72E7-D
Abstract
Against the rules: During the hundred years following Sabatier's groundbreaking work on catalytic hydrogenation, syn delivery of the H atoms to the π system of a substrate remained the governing stereochemical rule. An exception has now be found with the use of cationic [Cp*Ru] templates, which accounts for the first practical, functional-group-tolerant, broadly applicable and highly E-selective semihydrogenation method for alkynes (see scheme).