Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes

Inés, B.; Palomas Dona, David; Holle, Sigrid; Steinberg, Sebastian; Nicasio Collazo, Juan Antonio; Alcarazo, M.

doi:10.1002/anie.201205348

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Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes

MPS-Authors

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Inés, B.
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Palomas Dona, David
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58631

Holle, Sigrid
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons101538

Steinberg, Sebastian
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons132843

Nicasio Collazo, Juan Antonio
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58392

Alcarazo, M.
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Inés, B., Palomas Dona, D., Holle, S., Steinberg, S., Nicasio Collazo, J. A., & Alcarazo, M. (2012). Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(49), 12367-12369. doi:10.1002/anie.201205348.

引用: https://hdl.handle.net/11858/00-001M-0000-000E-7934-B

要旨

The poorer, the better: A metal-free catalytic procedure for the reduction of electron-poor allenes and alkenes has been developed. The method employs a frustrated Lewis pair based catalyst. 1,4-Diazabicyclo[2.2.2]octane (DABCO)/B(C₆F₅)₃ was shown to be the best combination in optimization studies.