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Metal-graphite reagents in carbohydrate chemistry, IX. Fragmentations of 1-deoxy-1-iodo-2,3;4,5-di-O-isopropylidene pentitols

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Fürstner, A. (1990). Metal-graphite reagents in carbohydrate chemistry, IX. Fragmentations of 1-deoxy-1-iodo-2,3;4,5-di-O-isopropylidene pentitols. Tetrahedron Letters, 31(26), 3735-3738. doi:10.1016/S0040-4039(00)97457-4.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000E-7C05-8
Abstract
Compounds 1 and 3, each readily available in both enantiomeric forms smoothly fragment on treatment with zinc/silver-graphite or potassium-graphite laminate (C8K), respectively, thus affording the full set of stereoisomeric 1,2-O-isopropylidene-pent-4-enitols.