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The Role of Palladium Dynamics in the Surface Catalysis of Coupling Reactions

MPG-Autoren
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Shao,  Lidong
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Zhang,  Wei
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Su,  Dang Sheng
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
Shenyang National Laboratory for Materials Science Institute of Metal Research, Chinese Academy of Science;

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Zitation

Shao, L., Zhang, B. S., Zhang, W., Hong, S. Y., Schlögl, R., & Su, D. S. (2013). The Role of Palladium Dynamics in the Surface Catalysis of Coupling Reactions. Angewandte Chemie International Edition, 52(7), 2114-2117. doi:10.1002/anie.201207362.


Zitierlink: https://hdl.handle.net/11858/00-001M-0000-000E-7F68-3
Zusammenfassung
More than scratching the surface: The mechanism by which supported Pd nanoparticles (PdNPs) catalyze cross-coupling reactions is the subject of debate. The changes in supported PdNPs during coupling reactions are studied by exploiting modified carbon nanotubes (CNTs) as support materials. After catalysis, CNTs with scratched walls and PdNPs with surface crystalline distortions were discovered, offering insights into the catalytic mechanism.