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C1-Substituted N-Alkyl Tetrahydroisoquinoline Derivatives through V-Catalyzed Oxidative Coupling

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Jones,  Kevin Mark
Research Group Klußmann, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Karier,  Pol
Research Group Klußmann, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Klussmann,  Martin
Research Group Klußmann, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Jones, K. M., Karier, P., & Klussmann, M. (2012). C1-Substituted N-Alkyl Tetrahydroisoquinoline Derivatives through V-Catalyzed Oxidative Coupling. ChemCatChem, 4(1), 51-54. doi:10.1002/cctc.201100324.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000E-F259-4
Abstract
In the THIQ of it:N-Alkyl tetrahydroisoquinolines are oxidatively coupled with a variety of nucleophiles in the presence of m-CPBA and [VO(acac)2]. This method has been applied to the synthesis of the opioid methopholine.