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Journal Article

Practical separation of alcohol-ester mixtures using Deep-Eutectic-Solvents


Leitner,  Walter
Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany ;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Maugeri, Z., Leitner, W., & Hammer, M. (2012). Practical separation of alcohol-ester mixtures using Deep-Eutectic-Solvents. TETRAHEDRON LETTERS, 53(51), 6968-6971. doi:10.1016/j.tetlet.2012.10.044.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000E-F2B7-1
Deep-Eutectic-Solvents (DES) were assessed for the separation of alcohol-ester mixtures, for example those typically obtained from catalytic kinetic resolutions of racemic alcohols. DES can efficiently dissolve molecules containing hydrogen-bond-donors (alcohols), whereas esters remain as second phase. By using this concept, tedious separation chromatographic steps may be easily overcome with bio-based non-hazardous solvents. (C) 2012 Elsevier Ltd. All rights reserved.