English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Steady-state and forced periodic operation of solid electrolyte membrane reactors for selective oxidation of n-butane to maleic anhydride

MPS-Authors
/persons/resource/persons86413

Munder,  Barbara
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

/persons/resource/persons86450

Rihko-Struckmann,  Liisa
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

/persons/resource/persons86497

Sundmacher,  Kai
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Munder, B., Rihko-Struckmann, L., & Sundmacher, K. (2007). Steady-state and forced periodic operation of solid electrolyte membrane reactors for selective oxidation of n-butane to maleic anhydride. Chemical Engineering Science, 62(18-20 ), 5663-5668. doi:10.1016/j.ces.2007.01.042.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0013-9919-A
Abstract
Experimental results obtained with a bilayer-solid electrolyte membrane reactor (bilayer-SEMR) are analysed based on a 1D+1D reactor model and attainable yields in steady-state and forced-periodic operation modes are determined. Optimal steady-state operation conditions are predicted in the range of high Damköhler numbers and oxidizing conditions. Forced-periodic operation of bilayer-SEMRs, which is easily established via the electric current, leads to a significant selectivity enhancement, but has to be critically rated with respect to energy expenses needed under electrochemical-oxygen-pumping conditions. copyright 2007 Elsevier Ltd. All rights reserved. [accessed February 8th 2013]