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Dynamic simulation of reactive distillation processes with liquid-liquid phase splitting

MPS-Authors
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Radulescu,  G.
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Petroleum – Gas University of Ploiesti, Ploiesti, Romania;

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Gangadwala,  J.
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

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Kienle,  A.
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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Steyer,  Frank
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

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Sundmacher,  Kai
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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Citation

Radulescu, G., Gangadwala, J., Kienle, A., Steyer, F., & Sundmacher, K. (2006). Dynamic simulation of reactive distillation processes with liquid-liquid phase splitting. Buletinul Universitatii Petrol-Gaze din Ploiesti. Seria Tehnica, 58(1), 1-12.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0013-9ADC-A
Abstract
This work presents a modern modeling approach for reactive distillation processes with potential phase splitting. It is based on a classical model (pseudo-homogeneous) in connection with a robust and reliable phase splitting algorithm (through homotopy-continuation method), performed at each simulation step. Model validation stage and a simple case-study (by applying the new approach to a reactive distillation column for waste water treatment) are also presented. All simulation scenarios revealed a good agreement between simulation results and the real system behavior, much better than using a classical pseudo-homogeneous mathematical model.