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MTBE decomposition in a reactive distillation column

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Qi,  Zhiwen
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
State Key Lab. of Chem. Eng., School of Chem. Eng., East China Univ. of Science and Technology, Shanghai , China;

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Kienle,  A.
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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Stein,  E.
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;

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Sundmacher,  Kai
Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society;
Otto-von-Guericke-Universität Magdeburg, External Organizations;

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Citation

Qi, Z., Kienle, A., Stein, E., Mohl, K. D., Tuchlenski, A., & Sundmacher, K. (2003). MTBE decomposition in a reactive distillation column. In ISMR3 - CCRE18: joint research symposium of the 3rd International Symposium on Multifunctional Reactors and the 18th Colloquia on Chemical Reaction Engineering (pp. 29-33).


Cite as: https://hdl.handle.net/11858/00-001M-0000-0013-9F9B-1
Abstract
MTBE decomposition in reactive distillation columns is investigated with considering side reactions. Quasi-homogeneous as well as heterogeneous column models are applied for a packed column. In the latter, the multi-component intra-particle mass transport phenomena are accounted for. Continuation methods are used to study the influence of parameters. The catalyst holdup should be very low in order to fully convert MTBE with hight selectivity towards the desired products.