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Journal Article

(S)-(–)-2,2′-Bis(2-methyl­allyl­­oxy)-1,1′-binaphth­yl

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Citation

Ricken, S., Angelovski, G., Schürmann, M., Preut, H., & Eilbracht, P. (2007). (S)-(–)-2,2′-Bis(2-methyl­allyl­­oxy)-1,1′-binaphth­yl. Acta Crystallographica Section E, 63(2), o551-o552. doi:10.1107/S1600536806055498.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0013-CE99-E
Abstract
The chiral title compound, C28H26O2, with potential uses in the synthesis of aza­macroheterocycles, shows a locked S-configuration for the binaphthyl unit. The diolefinic building blocks were prepared as diallylic ethers of (S)-1,1‘-binaphthol. The dihedral angle between the least-squares planes of the bicyclic ring systems is 68.53 (3)°. The mol­ecule resides on a twofold axis.