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Aerobic C-H Amination of Tetrahydrocarbazole Derivatives via Photochemically Generated Hydroperoxides

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Gulzar,  Naeem
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Klussmann,  Martin
Research Group Klußmann, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Gulzar, N., & Klussmann, M. (2013). Aerobic C-H Amination of Tetrahydrocarbazole Derivatives via Photochemically Generated Hydroperoxides. Organic & Biomolecular Chemistry, 11(27), 4516-4520. doi:10.1039/c3ob40919h.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A51B-5
Abstract
A Brønsted acid catalyzed C–H functionalization via Intermediate PeroxideS (CHIPS), generated photochemically, allows the oxidative coupling of indole derivatives with a variety of nitrogen nucleophiles. The reaction can be performed in one pot and requires only visible light, elemental oxygen, a Brønsted acid and a photosensitizer. The method can be applied to an efficient synthesis of some biologically active compounds.