Reversed Chemoselectivity in Titanium-induced Coupling Reactions: Syntheses of 
Salvadoricine and Diazepam

Fürstner, Alois; Jumbam, Denis N.

doi:10.1039/C39930000211

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Reversed Chemoselectivity in Titanium-induced Coupling Reactions: Syntheses of Salvadoricine and Diazepam

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Fürstner, A., & Jumbam, D. N. (1993). Reversed Chemoselectivity in Titanium-induced Coupling Reactions: Syntheses of Salvadoricine and Diazepam. Journal of the Chemical Society, Chemical Communications, (2), 211-212. doi:10.1039/C39930000211.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-A48F-7

Abstract

Titanium/graphite-promoted indole formation is favoured over inter- as well as intra-molecular McMurry coupling as evidenced by chemoselective syntheses of compounds 2 and 5–7.