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Efficient proline-catalyzed Michael additions of unmodified ketones to nitro olefins

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Departments of Chemistry and Molecular Biology, The Scripps Research Institute;

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Citation

List, B., Pojarliev, P., & Martin, H. J. (2001). Efficient proline-catalyzed Michael additions of unmodified ketones to nitro olefins. Organic Letters, 3(16), 2423-2425. doi:10.1021/ol015799d.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A4D9-0
Abstract
Here we describe the proline-catalyzed Michael addition of unmodified ketones to nitro olefins. This novel reaction provides γ-nitro ketones in modest enantioselectivity yet excellent yields.