Direct Catalytic Asymmetric α-Amination of Aldehydes

List, Benjamin

doi:10.1021/ja0261325

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Direct Catalytic Asymmetric α-Amination of Aldehydes

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List, B. (2002). Direct Catalytic Asymmetric α-Amination of Aldehydes. Journal of the American Chemical Society, 124(20), 5656-5657. doi:10.1021/ja0261325.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-A4CD-C

Abstract

The first direct catalytic asymmetric α-amination of aldehydes is described herein. α-Unbranched aldehydes react in this novel proline-catalyzed reaction with dialkyl azodicarboxylates to give α-amino aldehydes in excellent yields and enantioselectivities.