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Syntheses of Camalexin, Indolopyridocoline and Flavopereirine

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Ernst,  Andreas
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., & Ernst, A. (1995). Syntheses of Camalexin, Indolopyridocoline and Flavopereirine. Tetrahedron, 51(3), 773-786. doi:10.1016/0040-4020(94)00987-6.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A485-C
Abstract
A short synthetic route to the phytoalexin camalexin 7 and a convergent approach to the alkaloids indolopyridocoline 8, 6,7-dihydroflavopereirine 15 and flavopereirine 9 are presented. Starting from well accessible precursors, these total syntheses highlight the preparative potential of a new method for indole synthesis based on the formation of the C2-C3 bond by low-valent titanium induced reductive coupling of oxo-amides.