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Stabilization of a Two-Coordinate [GeCl]+ Cation by Simultaneous σ and π Donation from a Monodentate Carbodiphosphorane

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Khan,  Shabana
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Gopakumar,  Gopinadhanpillai
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Thiel,  Walter
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Alcarazo,  Manuel
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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anie_201300677_sm_miscellaneous_information.pdf
(Supplementary material), 3MB

Citation

Khan, S., Gopakumar, G., Thiel, W., & Alcarazo, M. (2013). Stabilization of a Two-Coordinate [GeCl]+ Cation by Simultaneous σ and π Donation from a Monodentate Carbodiphosphorane. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 52(21), 5644-5647. doi:10.1002/anie.201300677.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A3EB-0
Abstract
Give me four: The synthesis, structure, and reactivity of [GeCl]+ and [SnCl]+ cations bearing a carbodiphosphorane as ancillary ligand are presented. In the Ge compound, simultaneous σ and π donation from the carbodiphosphorane to Ge is observed (see HOMO (left) and HOMO−1 (right); C black, H white, P orange, Cl green, Ge purple (not visible)), whereas only the σ dative component is present in the Sn analogue.