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Journal Article

Trends in the Binding Strength of Surface Species on Nanoparticles: How Does the Adsorption Energy Scale with the Particle Size?

MPS-Authors
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Peter,  Matthias
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Flores Camacho,  Jose Manuel
Chemical Physics, Fritz Haber Institute, Max Planck Society;
Instituto de Investigación en Comunicación Óptica-UASLP;

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Adamovski,  Sergey
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Dostert,  Karl-Heinz
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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O'Brien,  Casey
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Schauermann,  Swetlana
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Freund,  Hans-Joachim
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Citation

Peter, M., Flores Camacho, J. M., Adamovski, S., Ono, L. K., Dostert, K.-H., O'Brien, C., et al. (2013). Trends in the Binding Strength of Surface Species on Nanoparticles: How Does the Adsorption Energy Scale with the Particle Size? Angewandte Chemie International Edition, 52(19), 5175-5179. doi:10.1002/anie.201209476.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-61D5-C
Abstract
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The binding energy of oxygen on Pd nanoparticles was measured by a direct calorimetric method as a function of the particle size. The reduced dimensionality of the Pd substrate results in two counteracting trends: an increase of the Pd[BOND]O binding strength due to a change of the local configuration of the adsorption site and a strong decrease of the Pd[BOND]O bonding due to the reduction of the cluster size.