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Base-Promoted Internal Redox-Cyclisation Reactions

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Shaaban,  Saad
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Peng,  Bo
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Maulide,  Nuno
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Shaaban, S., Peng, B., & Maulide, N. (2013). Base-Promoted Internal Redox-Cyclisation Reactions. Synlett, 24(13), 1722-1724. doi:10.1055/s-0033-1339313.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-A395-0
Abstract
A new internal, base-mediated redox-cyclisation reaction has been discovered and developed. In this transformation, the sacrificial reduction of an alkynyl moiety to an alkene allows direct functionalisation of an α-amino C-H bond. This approach allows the preparation of several 1,3-oxazinane derivatives in an atom-­efficient manner.