Palladium-Catalyzed Allylic Substitution at Four-Membered-Ring Systems: 
Formation of η1-Allyl Complexes and Electrocyclic Ring Opening

Audisio, Davide; Gopakumar, Gopinadhanpillai; Xie, Langui; Alves, Luís G.; Wirtz, Cornelia; Martins, Ana M.; Thiel, Walter; Farès, Christophe; Maulide, Nuno

doi:10.1002/anie.201301034

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Palladium-Catalyzed Allylic Substitution at Four-Membered-Ring Systems: Formation of η¹-Allyl Complexes and Electrocyclic Ring Opening

MPS-Authors

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Audisio, Davide
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58583

Gopakumar, Gopinadhanpillai
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons132919

Xie, Langui
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Wirtz, Cornelia
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons59045

Thiel, Walter
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58537

Farès, Christophe
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58809

Maulide, Nuno
Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Audisio, D., Gopakumar, G., Xie, L., Alves, L. G., Wirtz, C., Martins, A. M., Thiel, W., Farès, C., & Maulide, N. (2013). Palladium-Catalyzed Allylic Substitution at Four-Membered-Ring Systems: Formation of η¹-Allyl Complexes and Electrocyclic Ring Opening. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 52(24), 6313-6316. doi:10.1002/anie.201301034.

引用: https://hdl.handle.net/11858/00-001M-0000-0014-A35D-1

要旨

Caught in the act: A series of unique η¹-allyl palladium complexes of four-membered cyclic systems bearing β-hydrogens were prepared (see structure). Their unusual structure, reactivity, and unprecedented propensity for undergoing pericyclic reactions were uncovered.