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Journal Article

Esterification of carboxylate-based ionic liquids with alkyl halides

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Leitner,  Walter
Institut für Technische und Makromolekulare Chemie, RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Zhao, B., Greiner, L., & Leitner, W. (2011). Esterification of carboxylate-based ionic liquids with alkyl halides. Chemical Communications, 47(10), 2973-2975. doi:10.1039/c0cc04798h.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-A312-7
Abstract
A facile reaction of 1-ethyl 3-methylimidazolium acetate ([EMIm]Ac) with dichloromethane at room temperature was observed with esters among the products. This esterification can be exploited for mild solvent-free esterification with a range of other carboxylate-based ionic liquids and alkyl halides.