SELECTIVE ENZYMATIC DEPROTECTION OF HYDROXY-GROUPS AND AMINO-GROUPS IN 
CARBOHYDRATES AND NUCLEOSIDES

Waldmann, Herbert; HEUSER, A; REIDEL, A

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SELECTIVE ENZYMATIC DEPROTECTION OF HYDROXY-GROUPS AND AMINO-GROUPS IN CARBOHYDRATES AND NUCLEOSIDES

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Waldmann, Herbert
Abt. IV: Chemische Biologie, Max Planck Institute of Molecular Physiology, Max Planck Society;

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Citation

Waldmann, H., HEUSER, A., & REIDEL, A. (1994). SELECTIVE ENZYMATIC DEPROTECTION OF HYDROXY-GROUPS AND AMINO-GROUPS IN CARBOHYDRATES AND NUCLEOSIDES. SYNLETT, (1), 65-67.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-9C82-F

Abstract

The enzyme acetyl esterase from the flavedo of oranges (EC 3.1.1.6) chemo- and regioselectively removes acetyl groups from carbohydrates and nucleosides. The chemoselective enzymatic liberation of the amino functions present in the nucleobases of O-acetylated nucleosides is achieved by penicillin G acylase (EC 3.5.1.11) mediated hydrolysis of the corresponding phenylacetamides.