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Synthesis of 2-deoxy and 2,6-dideoxy glycosides under neutral conditions in LiClO4/Et2O mixtures

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Waldmann,  Herbert
Abt. IV: Chemische Biologie, Max Planck Institute of Molecular Physiology, Max Planck Society;

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Citation

Schene, H., & Waldmann, H. (1998). Synthesis of 2-deoxy and 2,6-dideoxy glycosides under neutral conditions in LiClO4/Et2O mixtures. CHEMICAL COMMUNICATIONS, (24), 2759-2760. doi:10.1039/a807734g.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0014-9CB1-3
Abstract
Glycosides of 2-deoxy and 2,6-dideoxy carbohydrates were built up in high yields and with high stereoselectivity in 0.1 M LiClO4/Et2O mixtures; the glycosidations proceed under neutral conditions and without need for an additional promoter such as a strong Lewis acid, a heavy metal salt or an alkylating reagent.